List of Publications
Previous research
A novel luminescent optical fibre probe based on immobilized tridentate bis(phosphinic amide)-phosphine oxide for europium(III) ion aqueous detection in situ
Sainz-Gonzalo F.J., Elosua C., Fernández-Sánchez J.F., Popovici C., Fernández I., Ortiz F.L., Arregui F.J., Matias I.R., Fernández-Gutiérrez A.
Sensors and Actuators B: Chemical, 2012, 173, 254 - 261.
http://dx.doi.org/10.1016/j.snb.2012.07.008
URL: http://www.sciencedirect.com/science/article/pii/S0925400512006831
Transformations of diphenylphosphinothioic acid tertiary amides mediated by directed ortho metallation
Hajjouji Hel, Belmonte E, Garcia-Lopez J, Fernandez I, Iglesias MJosé, Roces L, García-Granda S, Laghdach AEl, Ortiz FLópez.
Org. Biomol. Chem., 2012, 10, 5647-5658.
10.1039/C2OB25395J
Oxidative Addition of Carbon--Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex
Darmon JM, S. Stieber CE, Sylvester KT, Fernández I, Lobkovsky E, Semproni SP, Bill E, Wieghardt K, DeBeer S, Chirik PJ.
Journal of the American Chemical Society, 2012, 134, 17125-17137.
10.1021/ja306526d
Development of polymeric sensing films based on a tridentate bis(phosphinic amide)-phosphine oxide for detecting europium(iii) in water
Sainz-Gonzalo F.J, Casimiro M., Popovici C., Rodriguez-Dieguez A., Fernandez-Sanchez J.F, Fernández I., López-Ortiz F., Fernandez-Gutierrez A.
Dalton Trans., 2012, 41, 6735-6748.
10.1039/C2DT30257H
1H,89Y HMQC and Further NMR Spectroscopic and X-ray Diffraction Investigations on Yttrium-Containing Complexes Exhibiting Various Nuclearities
Loble MW, Casimiro M, Thielemann DT, Oña-Burgos P, Fernandez I, Roesky PW, Breher F.
Chemistry -- A European Journal, 2012, 18, 5325--5334.
10.1002/chem.201102636
Synthesis and structure of tridentate bis(phosphinic amide)-phosphine oxide complexes of yttrium nitrate. Applications of 31P,89Y NMR methods in structural elucidation in solution
Popovici C, Fernandez I, Oña-Burgos P, Roces L, García-Granda S, Ortiz FLopez.
Dalton Trans., 2011, 40, 6691-6703.
10.1039/C1DT10194C
31P,89Y Shift correlation. Application to the speciation of yttrium complexes with triphenylphosphine oxide
Fernandez I, Yanez-Rodriguez V, Ortiz FLopez.
Dalton Trans., 2011, 40, 2425-2428.
10.1039/C0DT01733G
A triangulopalladium cluster consisting of [small mu ]3-capping silyl ligands
Armbruster F, Meyer J, Baldes A, Burgos POna, Fernandez I, Breher F.
Chem. Commun., 2011, 47, 221-223.
10.1039/C002435J
New amino acid ligated yttrium hydroxy clusters
Thielemann DT, Fernandez I, Roesky PW.
Dalton Trans., 2010, 39, 6661-6666.
10.1039/C001464H
Octahedral iron(ii) phthalocyanine complexes: multinuclear NMR and relevance as NO2 chemical sensors
Oña-Burgos P, Casimiro M, Fernandez I, Navarro AValero, Sanchez JFFernand, Carretero ASegura, Gutierrez AFernandez.
Dalton Trans., 2010, 39, 6231-6238.
10.1039/B924429H
Solution and Computed Structure of o-Lithium N,N-Diisopropyl-P,P-diphenylphosphinic Amide. Unprecedented Li-O-Li-O Self-Assembly of an Aryllithium
Fernandez I, Oña-Burgos P, Oliva JM, Ortiz FLopez.
Journal of the American Chemical Society, 2010, 132, 5193-5204.
10.1021/ja910556a
Enantioselective Desymmetrization of Diphenylphosphinamides via (−)-Sparteine-Mediated Ortho-Lithiation. Synthesis of P-Chiral Ligands
Popovici C, Oña-Burgos P, Fernandez I, Roces L, García-Granda S, Iglesias MJosé, Ortiz FLopez.
Organic Letters, 2010, 12, 428-431.
10.1021/ol902545q
Solution NMR structural study of a mixed aggregate of N-lithium triphenylphosphazene and lithium bromide
Fernandez I, Davidson MG, Price RD, Ortiz FLopez.
Dalton Trans., 2009, , 2438-2442.
10.1039/B821424G
Neutral and cationic main group element cages of germanium(ii) with pyrazolyl ligands: solid state structures, DFT calculations and advanced solution NMR investigations
Krummenacher I, Fernandez I, Ruegger H, Weigend F, Breher F.
Dalton Trans., 2009, , 5335-5347.
10.1039/B901711A
Syntheses, structures, and reactivity of poly(pyrazolyl)silanes, -disilanes, and the ambidentate [small kappa]1Si/[small kappa]3N-coordinating tris(3,5-dimethylpyrazolyl)silanide ligand [Si(3,5-Me2pz)3]- (MeTpsd)
Armbruster F, Fernandez I, Breher F.
Dalton Trans., 2009, , 5612-5626.
10.1039/B906333A
Ferrocene–β-Cyclodextrin Conjugates: Synthesis, Supramolecular Behavior, and Use as Electrochemical Sensors
Casas-Solvas J M., Ortiz-Salmerón E, Fernandez I, García-Fuentes L, Santoyo-González F, Vargas-Berenguel A.
Chemistry – A European Journal, 2009, 15, 8146–8162.
10.1002/chem.200900593
Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3 and FeCH2CMe3 Derivatives
Fernandez I, Trovitch RJ, Lobkovsky E, Chirik PJ.
Organometallics, 2008, 27, 109-118.
10.1021/om700913g
Phosphinamide-Directed Benzylic Lithiation. Application to the Synthesis of Peptide Building Blocks
Burgos POña, Fernandez I, Iglesias MJosé, García-Granda S, Ortiz FLópez.
Organic Letters, 2008, 10, 537-540.
10.1021/ol7028096
Asymmetric Deprotonation-Substitution of N-Pop-benzylamines Using [RLi/(-)-Sparteine]. Enantioselective Sequential Reactions and Synthesis of N-Heterocycles
Oña-Burgos P, Fernandez I, Roces L, Torre-Fernández L, García-Granda S, López-Ortiz F.
Organic Letters, 2008, 10, 3195-3198.
10.1021/ol801027p
Nucleophilic Dearomatizing (DNAr) Reactions of Aromatic C,H-Systems. A Mature Paradigm in Organic Synthesis
Ortiz FLópez, Iglesias MJosé, Fernandez I, Sánchez CMAndúja, Gómez GRuiz.
Chemical Reviews, 2007, 107, 1580-1691.
10.1021/cr030207l
A Tetrameric Lithiated Phosphazene Containing a Lithium Atom Bound Exclusively to Four sp3-Hybridized Carbanionic Centers: A Key Intermediate for Understanding Structure-Reactivity Relationships of Phosphazenyllithium Compounds
Gómez GRuiz, Fernandez I, Ortiz FLópez, Price RD, Davidson MG, Mahon MF, Howard JAK.
Organometallics, 2007, 26, 514-518.
10.1021/om0608354
Allylic Alcohols as Substrate for Ruthenium-Catalyzed CC Coupling Allylation Reactions. Preliminary Communication
Ignacio Fernández, Schott D, Gruber S, Pregosin P S.
Helvetica Chimica Acta, 2007, 90, 271–276.
10.1002/hlca.200790030
C[small alpha],Cortho-Dimetalated phosphazene complexes
Lopez JGarcia, Fernandez I, Ruiz MSerrano, Ortiz FLopez.
Chem. Commun., 2007, , 4674-4676.
10.1039/B707320H
Synthesis, X-ray Studies, and Catalytic Allylic Amination Reactions with Ruthenium(IV) Allyl Carbonate Complexes
Fernandez I, Hermatschweiler R, Pregosin PS, Albinati A, Rizzato S.
Organometallics, 2006, 25, 323-330.
10.1021/om050749o
1H and 19F PGSE diffusion and HOESY NMR studies on cationic palladium (II) 1,3-diphenylallyl complexes in THF solution
Fernandez I, Pregosin PS.
Magnetic Resonance in Chemistry, 2006, 44, 76-82.
10.1002/mrc.1729
Solution NMR and X-Ray Structural Studies on Phthalocyaninatoiron Complexes
Fernandez I, Pregosin P S., Albinati A, Rizzato S, Spichiger-Keller U E., Nezel T, Fernández-Sánchez J F.
Helvetica Chimica Acta, 2006, 89, 1485–1496.
10.1002/hlca.200690153
High-Yield Ruthenium-Catalyzed Friedel–Crafts-Type Allylation Reactions Using Dicationic RuIV Catalysts
Fernandez I, Hermatschweiler R, Breher F, Pregosin PS, Veiros LF, Calhorda MJosé.
Angewandte Chemie International Edition, 2006, 45, 6386–6391.
10.1002/anie.200600447
X-ray Diffraction, PGSE Diffusion, and Related NMR Studies on a Series of Cp*-Based Ru(IV)(Cp*)(η3-CH2-CH-CHPh) Allyl Complexes
Fernandez I, Pregosin PS, Albinati A, Rizzato S.
Organometallics, 2006, 25, 4520-4529.
10.1021/om060448u
Catalytic Allylic Alkylation and Allylic Phenolation Reactions with Ruthenium Complexes. Solid-State Structures of a Model Catalytic DMF Intermediate, [Ru(Cp*)(Cl)(η3-C3H5)(DMF)](PF6), and a New Tetranuclear Salt, [Ru(Cp)Ru(Cp)(η6-p-CH3C6H4CN)3](PF6)4
Hermatschweiler R, Fernandez I, Pregosin PS, Breher F.
Organometallics, 2006, 25, 1440-1447.
10.1021/om051050l
Synthesis, X-ray Studies, and Catalytic Allylic Amination Reactions with Ruthenium(IV) Allyl Carbonate Complexes
Fernandez I, Hermatschweiler R, Pregosin PS, Albinati A, Rizzato S.
Organometallics, 2006, 25, 323-330.
10.1021/om050749o
Mechanism of Anionic Dearomatizing Reactions of Diphenylphosphinamide Derivatives: A Theoretical and Experimental Study
Ramallal AMorán, Fernandez I, Ortiz FLópez, González J.
Chemistry -- A European Journal, 2005, 11, 3022--3031.
10.1002/chem.200400987
7Li, 31P, and 1H Pulsed Gradient Spin-Echo (PGSE) Diffusion NMR Spectroscopy and Ion Pairing: On the Temperature Dependence of the Ion Pairing in Li(CPh3), Fluorenyllithium, and Li[N(SiMe3)2] amongst Other Salts
Fernandez I, Martínez-Viviente E, Breher F, Pregosin PS.
Chemistry – A European Journal, 2005, 11, 1495–1506.
10.1002/chem.200400867
Multinuclear PGSE Diffusion and Overhauser NMR Studies on a Variety of Salts in THF Solution
Fernandez I, Martínez-Viviente E, Pregosin PS.
Inorganic Chemistry, 2005, 44, 5509-5513.
10.1021/ic050523d
NMR, PGSE Diffusion, and X-ray Diffraction Studies of Lithium and Potassium Salts Derived from Diphenylphosphino(o-cyanophenyl)aniline and Their Crown Ether Complexes
Fernandez I, Breher F, Pregosin PS, Fei Z, Dyson PJ.
Inorganic Chemistry, 2005, 44, 7616-7623.
10.1021/ic050753s
Pulsed Gradient Spin-Echo (PGSE) Diffusion and 1H,19F Heteronuclear Overhauser Spectroscopy (HOESY) NMR Methods in Inorganic and Organometallic Chemistry: Something Old and Something New
Pregosin PS, Kumar P.GAnil, Fernandez I.
Chemical Reviews, 2005, 105, 2977-2998.
10.1021/cr0406716
Ruthenium-Catalyzed Allylic Alkylation Reactions: Carbonate-Based Catalysts and Intermediates
René Hermatschweiler and Ignacio Fernandez and Frank Breher and Paul S Pregosin and Luis F Veiros and Maria José Calhorda
Angewandte Chemie International Edition, 2005, 44, 4397–4400.
10.1002/anie.200500967
Unprecedented asymmetric induction through configurationally stable lithium N-([small alpha]-methylbenzyl)phosphinamides. A new entry to enantiomerically pure [gamma]-aminophosphinic acids and esters
Fernandez I, Gomez GRuiz, Alfonso I, Iglesias MJ, Ortiz FLopez.
Chem. Commun., 2005, , 5408-5410.
10.1039/B510685K
X-ray, 13C NMR, and DFT Studies on a Ruthenium(IV) Allyl Complex. Explanation for the Observed Control of Regioselectivity in Allylic Alkylation Chemistry
Hermatschweiler R, Fernandez I, Pregosin PS, Watson EJ, Albinati A, Rizzato S, Veiros LF, Calhorda MJosé.
Organometallics, 2005, 24, 1809-1812.
10.1021/om049057a
The First Mixed-Anion Complex of a Lithium Phosphazene: Synthesis and Crystal and Solution Structure of [(LiCH2P(Ph)2NPh)textperiodcentered(LiOC6H2-2,6-C(CH3)3-4-CH3)]2
Price R.D, Fernández I., López-Ortiz F., Davidson M.G, Cowan A.J, Howard J.AK.
ACS, 2004, 23, 5934–5938.
10.1021/om049608x
Deuterium Labelling and NMR Study of the Dearomatization of N-Alkyl-N-benzydiphenylphosphinamides through Anionic Cyclization. Ortho and Benzylic Lithiation Directed by Complex Induced Proximity Effects
Fernández I., González J., López-Ortiz F.
J. Am. Chem., 2004, 126, 12551–12564.
10.1021/ja039863t
7Li PGSE Diffusion Measurements on LiPPh2: a Solvent Dependence of the Structure
Fernández I., Martínez-Viviente E., Pregosin P.S.
JACS, 2004, 43, 4555–4557.
10.1021/ic049703y
X-ray and multinuclear NMR study of the mixed aggregate [(Ph2P(O)N(CH2Ph)CH3)textperiodcenteredLiOC6H2-2,6-C(CH3)32-4-CH3)textperiodcenteredC7H8]2: a model for the directed metalation of phosphinamides
Fernández I., F. Ortiz L, Price R.D, Bolton P., Davidson M.G.
Journal of Organometallic Chemistry, 2004, 689, 1890 - 1896.
http://dx.doi.org/10.1016/j.jorganchem.2004.03.013
URL: http://www.sciencedirect.com/science/article/pii/S0022328X0400186X
7Li,31P Shift correlation. Application to the structural assignment of benzyllithium complexes of N-methyl-N-benzylphosphinamide
Fernández I., F. Ortiz L.
Chem. Commun., 2004, , 1142-1143.
10.1039/B400994K