Previous Research

2012

A novel luminescent optical fibre probe based on immobilized tridentate bis(phosphinic amide)-phosphine oxide for europium(III) ion aqueous detection in situ

Sainz-Gonzalo F.J., Elosua C., Fernández-Sánchez J.F., Popovici C., Fernández I., Ortiz F.L., Arregui F.J., Matias I.R., Fernández-Gutiérrez A.

Sensors and Actuators B: Chemical, 2012, 173, 254 - 261. http://dx.doi.org/10.1016/j.snb.2012.07.008

URL: http://www.sciencedirect.com/science/article/pii/S0925400512006831

Transformations of diphenylphosphinothioic acid tertiary amides mediated by directed ortho metallation

Hajjouji Hel, Belmonte E, Garcia-Lopez J, Fernandez I, Iglesias MJosé, Roces L, García-Granda S, Laghdach AEl, Ortiz FLópez.

Org. Biomol. Chem., 2012, 10, 5647-5658. 10.1039/C2OB25395J

URL: http://dx.doi.org/10.1039/C2OB25395J

Oxidative Addition of Carbon--Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex

Darmon JM, S. Stieber CE, Sylvester KT, Fernández I, Lobkovsky E, Semproni SP, Bill E, Wieghardt K, DeBeer S, Chirik PJ.

Journal of the American Chemical Society, 2012, 134, 17125-17137. 10.1021/ja306526d

URL: http://dx.doi.org/10.1021/ja306526d

Development of polymeric sensing films based on a tridentate bis(phosphinic amide)-phosphine oxide for detecting europium(iii) in water

Sainz-Gonzalo F.J, Casimiro M., Popovici C., Rodriguez-Dieguez A., Fernandez-Sanchez J.F, Fernández I., López-Ortiz F., Fernandez-Gutierrez A.

Dalton Trans., 2012, 41, 6735-6748. 10.1039/C2DT30257H

URL: http://dx.doi.org/10.1039/C2DT30257H

1H,89Y HMQC and Further NMR Spectroscopic and X-ray Diffraction Investigations on Yttrium-Containing Complexes Exhibiting Various Nuclearities

Loble MW, Casimiro M, Thielemann DT, Oña-Burgos P, Fernandez I, Roesky PW, Breher F.

Chemistry -- A European Journal, 2012, 18, 5325--5334. 10.1002/chem.201102636

URL: http://dx.doi.org/10.1002/chem.201102636

2011

Synthesis and structure of tridentate bis(phosphinic amide)-phosphine oxide complexes of yttrium nitrate. Applications of 31P,89Y NMR methods in structural elucidation in solution

Popovici C, Fernandez I, Oña-Burgos P, Roces L, García-Granda S, Ortiz FLopez.

Dalton Trans., 2011, 40, 6691-6703. 10.1039/C1DT10194C

URL: http://dx.doi.org/10.1039/C1DT10194C

31P,89Y Shift correlation. Application to the speciation of yttrium complexes with triphenylphosphine oxide

Fernandez I, Yanez-Rodriguez V, Ortiz FLopez.

Dalton Trans., 2011, 40, 2425-2428. 10.1039/C0DT01733G

URL: http://dx.doi.org/10.1039/C0DT01733G

A triangulopalladium cluster consisting of [small mu ]3-capping silyl ligands

Armbruster F, Meyer J, Baldes A, Burgos POna, Fernandez I, Breher F.

Chem. Commun., 2011, 47, 221-223. 10.1039/C002435J

URL: http://dx.doi.org/10.1039/C002435J

2010

New amino acid ligated yttrium hydroxy clusters

Thielemann DT, Fernandez I, Roesky PW.

Dalton Trans., 2010, 39, 6661-6666. 10.1039/C001464H

URL: http://dx.doi.org/10.1039/C001464H

Octahedral iron(ii) phthalocyanine complexes: multinuclear NMR and relevance as NO2 chemical sensors

Oña-Burgos P, Casimiro M, Fernandez I, Navarro AValero, Sanchez JFFernand, Carretero ASegura, Gutierrez AFernandez.

Dalton Trans., 2010, 39, 6231-6238. 10.1039/B924429H

URL: http://dx.doi.org/10.1039/B924429H

Solution and Computed Structure of o-Lithium N,N-Diisopropyl-P,P-diphenylphosphinic Amide. Unprecedented Li-O-Li-O Self-Assembly of an Aryllithium

Fernandez I, Oña-Burgos P, Oliva JM, Ortiz FLopez.

Journal of the American Chemical Society, 2010, 132, 5193-5204. 10.1021/ja910556a

URL: http://pubs.acs.org/doi/abs/10.1021/ja910556a

Enantioselective Desymmetrization of Diphenylphosphinamides via (−)-Sparteine-Mediated Ortho-Lithiation. Synthesis of P-Chiral Ligands

Popovici C, Oña-Burgos P, Fernandez I, Roces L, García-Granda S, Iglesias MJosé, Ortiz FLopez.

Organic Letters, 2010, 12, 428-431. 10.1021/ol902545q

URL: https://doi.org/10.1021/ol902545q

2009

Solution NMR structural study of a mixed aggregate of N-lithium triphenylphosphazene and lithium bromide

Fernandez I, Davidson MG, Price RD, Ortiz FLopez.

Dalton Trans., 2009, , 2438-2442. 10.1039/B821424G

URL: http://dx.doi.org/10.1039/B821424G

Neutral and cationic main group element cages of germanium(ii) with pyrazolyl ligands: solid state structures, DFT calculations and advanced solution NMR investigations

Krummenacher I, Fernandez I, Ruegger H, Weigend F, Breher F.

Dalton Trans., 2009, , 5335-5347. 10.1039/B901711A

URL: http://dx.doi.org/10.1039/B901711A

Syntheses, structures, and reactivity of poly(pyrazolyl)silanes, -disilanes, and the ambidentate [small kappa]1Si/[small kappa]3N-coordinating tris(3,5-dimethylpyrazolyl)silanide ligand [Si(3,5-Me2pz)3]- (MeTpsd)

Armbruster F, Fernandez I, Breher F.

Dalton Trans., 2009, , 5612-5626. 10.1039/B906333A

URL: http://dx.doi.org/10.1039/B906333A

Ferrocene–β-Cyclodextrin Conjugates: Synthesis, Supramolecular Behavior, and Use as Electrochemical Sensors

Casas-Solvas J M., Ortiz-Salmerón E, Fernandez I, García-Fuentes L, Santoyo-González F, Vargas-Berenguel A.

Chemistry – A European Journal, 2009, 15, 8146–8162. 10.1002/chem.200900593

URL: http://dx.doi.org/10.1002/chem.200900593

2008

Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3 and FeCH2CMe3 Derivatives

Fernandez I, Trovitch RJ, Lobkovsky E, Chirik PJ.

Organometallics, 2008, 27, 109-118. 10.1021/om700913g

URL: http://pubs.acs.org/doi/abs/10.1021/om700913g

Phosphinamide-Directed Benzylic Lithiation. Application to the Synthesis of Peptide Building Blocks

Burgos POña, Fernandez I, Iglesias MJosé, García-Granda S, Ortiz FLópez.

Organic Letters, 2008, 10, 537-540. 10.1021/ol7028096

URL: http://pubs.acs.org/doi/abs/10.1021/ol7028096

Asymmetric Deprotonation-Substitution of N-Pop-benzylamines Using [RLi/(-)-Sparteine]. Enantioselective Sequential Reactions and Synthesis of N-Heterocycles

Oña-Burgos P, Fernandez I, Roces L, Torre-Fernández L, García-Granda S, López-Ortiz F.

Organic Letters, 2008, 10, 3195-3198. 10.1021/ol801027p

URL: http://pubs.acs.org/doi/abs/10.1021/ol801027p

2007

Nucleophilic Dearomatizing (DNAr) Reactions of Aromatic C,H-Systems. A Mature Paradigm in Organic Synthesis

Ortiz FLópez, Iglesias MJosé, Fernandez I, Sánchez CMAndúja, Gómez GRuiz.

Chemical Reviews, 2007, 107, 1580-1691. 10.1021/cr030207l

URL: http://pubs.acs.org/doi/abs/10.1021/cr030207l

A Tetrameric Lithiated Phosphazene Containing a Lithium Atom Bound Exclusively to Four sp3-Hybridized Carbanionic Centers: A Key Intermediate for Understanding Structure-Reactivity Relationships of Phosphazenyllithium Compounds

Gómez GRuiz, Fernandez I, Ortiz FLópez, Price RD, Davidson MG, Mahon MF, Howard JAK.

Organometallics, 2007, 26, 514-518. 10.1021/om0608354

URL: http://pubs.acs.org/doi/abs/10.1021/om0608354

Allylic Alcohols as Substrate for Ruthenium-Catalyzed CC Coupling Allylation Reactions. Preliminary Communication

Ignacio Fernández, Schott D, Gruber S, Pregosin P S.

Helvetica Chimica Acta, 2007, 90, 271–276. 10.1002/hlca.200790030

URL: http://dx.doi.org/10.1002/hlca.200790030

C[small alpha],Cortho-Dimetalated phosphazene complexes

Lopez JGarcia, Fernandez I, Ruiz MSerrano, Ortiz FLopez.

Chem. Commun., 2007, , 4674-4676. 10.1039/B707320H

URL: http://dx.doi.org/10.1039/B707320H

2006

Synthesis, X-ray Studies, and Catalytic Allylic Amination Reactions with Ruthenium(IV) Allyl Carbonate Complexes

Fernandez I, Hermatschweiler R, Pregosin PS, Albinati A, Rizzato S.

Organometallics, 2006, 25, 323-330. 10.1021/om050749o

URL: http://pubs.acs.org/doi/abs/10.1021/om050749o

1H and 19F PGSE diffusion and HOESY NMR studies on cationic palladium (II) 1,3-diphenylallyl complexes in THF solution

Fernandez I, Pregosin PS.

Magnetic Resonance in Chemistry, 2006, 44, 76-82. 10.1002/mrc.1729

URL: http://dx.doi.org/10.1002/mrc.1729

Solution NMR and X-Ray Structural Studies on Phthalocyaninatoiron Complexes

Fernandez I, Pregosin P S., Albinati A, Rizzato S, Spichiger-Keller U E., Nezel T, Fernández-Sánchez J F.

Helvetica Chimica Acta, 2006, 89, 1485–1496. 10.1002/hlca.200690153

URL: http://dx.doi.org/10.1002/hlca.200690153

High-Yield Ruthenium-Catalyzed Friedel–Crafts-Type Allylation Reactions Using Dicationic RuIV Catalysts

Fernandez I, Hermatschweiler R, Breher F, Pregosin PS, Veiros LF, Calhorda MJosé.

Angewandte Chemie International Edition, 2006, 45, 6386–6391. 10.1002/anie.200600447

URL: http://dx.doi.org/10.1002/anie.200600447

X-ray Diffraction, PGSE Diffusion, and Related NMR Studies on a Series of Cp-Based Ru(IV)(Cp)(η3-CH2-CH-CHPh) Allyl Complexes

Fernandez I, Pregosin PS, Albinati A, Rizzato S.

Organometallics, 2006, 25, 4520-4529. 10.1021/om060448u

URL: http://pubs.acs.org/doi/abs/10.1021/om060448u

Catalytic Allylic Alkylation and Allylic Phenolation Reactions with Ruthenium Complexes. Solid-State Structures of a Model Catalytic DMF Intermediate, [Ru(Cp*)(Cl)(η3-C3H5)(DMF)](PF6), and a New Tetranuclear Salt, [Ru(Cp)Ru(Cp)(η6-p-CH3C6H4CN)3](PF6)4

Hermatschweiler R, Fernandez I, Pregosin PS, Breher F.

Organometallics, 2006, 25, 1440-1447. 10.1021/om051050l

URL: http://pubs.acs.org/doi/abs/10.1021/om051050l

2005

Synthesis, X-ray Studies, and Catalytic Allylic Amination Reactions with Ruthenium(IV) Allyl Carbonate Complexes

Fernandez I, Hermatschweiler R, Pregosin PS, Albinati A, Rizzato S.

Organometallics, 2006, 25, 323-330. 10.1021/om050749o

URL: http://pubs.acs.org/doi/abs/10.1021/om050749o

Mechanism of Anionic Dearomatizing Reactions of Diphenylphosphinamide Derivatives: A Theoretical and Experimental Study

Ramallal AMorán, Fernandez I, Ortiz FLópez, González J.

Chemistry -- A European Journal, 2005, 11, 3022--3031. 10.1002/chem.200400987

URL: http://dx.doi.org/10.1002/chem.200400987

7Li, 31P, and 1H Pulsed Gradient Spin-Echo (PGSE) Diffusion NMR Spectroscopy and Ion Pairing: On the Temperature Dependence of the Ion Pairing in Li(CPh3), Fluorenyllithium, and Li[N(SiMe3)2] amongst Other Salts

Fernandez I, Martínez-Viviente E, Breher F, Pregosin PS.

Chemistry – A European Journal, 2005, 11, 1495–1506. 10.1002/chem.200400867

URL: http://dx.doi.org/10.1002/chem.200400867

Multinuclear PGSE Diffusion and Overhauser NMR Studies on a Variety of Salts in THF Solution

Fernandez I, Martínez-Viviente E, Pregosin PS.

Inorganic Chemistry, 2005, 44, 5509-5513. 10.1021/ic050523d

URL: http://pubs.acs.org/doi/abs/10.1021/ic050523d

NMR, PGSE Diffusion, and X-ray Diffraction Studies of Lithium and Potassium Salts Derived from Diphenylphosphino(o-cyanophenyl)aniline and Their Crown Ether Complexes

Fernandez I, Breher F, Pregosin PS, Fei Z, Dyson PJ.

Inorganic Chemistry, 2005, 44, 7616-7623. 10.1021/ic050753s

URL: http://pubs.acs.org/doi/abs/10.1021/ic050753s

Pulsed Gradient Spin-Echo (PGSE) Diffusion and 1H,19F Heteronuclear Overhauser Spectroscopy (HOESY) NMR Methods in Inorganic and Organometallic Chemistry: Something Old and Something New

Pregosin PS, Kumar P.GAnil, Fernandez I.

Chemical Reviews, 2005, 105, 2977-2998. 10.1021/cr0406716

URL: http://pubs.acs.org/doi/abs/10.1021/cr0406716

Ruthenium-Catalyzed Allylic Alkylation Reactions: Carbonate-Based Catalysts and Intermediates

René Hermatschweiler and Ignacio Fernandez and Frank Breher and Paul S Pregosin and Luis F Veiros and Maria José Calhorda

Angewandte Chemie International Edition, 2005, 44, 4397–4400. 10.1002/anie.200500967

URL: http://dx.doi.org/10.1002/anie.200500967

Unprecedented asymmetric induction through configurationally stable lithium N-([small alpha]-methylbenzyl)phosphinamides. A new entry to enantiomerically pure [gamma]-aminophosphinic acids and esters

Fernandez I, Gomez GRuiz, Alfonso I, Iglesias MJ, Ortiz FLopez.

Chem. Commun., 2005, , 5408-5410. 10.1039/B510685K

URL: http://dx.doi.org/10.1039/B510685K

X-ray, 13C NMR, and DFT Studies on a Ruthenium(IV) Allyl Complex. Explanation for the Observed Control of Regioselectivity in Allylic Alkylation Chemistry

Hermatschweiler R, Fernandez I, Pregosin PS, Watson EJ, Albinati A, Rizzato S, Veiros LF, Calhorda MJosé.

Organometallics, 2005, 24, 1809-1812. 10.1021/om049057a

URL: http://pubs.acs.org/doi/abs/10.1021/om049057a

2004

The First Mixed-Anion Complex of a Lithium Phosphazene: Synthesis and Crystal and Solution Structure of [(LiCH2P(Ph)2NPh)textperiodcentered(LiOC6H2-2,6-C(CH3)3-4-CH3)]2

Price R.D, Fernández I., López-Ortiz F., Davidson M.G, Cowan A.J, Howard J.AK.

ACS, 2004, 23, 5934–5938. 10.1021/om049608x

URL: http://pubs.acs.org/doi/abs/10.1021/om049608x

Deuterium Labelling and NMR Study of the Dearomatization of N-Alkyl-N-benzydiphenylphosphinamides through Anionic Cyclization. Ortho and Benzylic Lithiation Directed by Complex Induced Proximity Effects

Fernández I., González J., López-Ortiz F.

J. Am. Chem., 2004, 126, 12551–12564. 10.1021/ja039863t

URL: http://pubs.acs.org/doi/full/10.1021/ja039863t

7Li PGSE Diffusion Measurements on LiPPh2: a Solvent Dependence of the Structure

Fernández I., Martínez-Viviente E., Pregosin P.S.

JACS, 2004, 43, 4555–4557. 10.1021/ic049703y

URL: http://pubs.acs.org/doi/abs/10.1021/ic049703y

X-ray and multinuclear NMR study of the mixed aggregate [(Ph2P(O)N(CH2Ph)CH3)textperiodcenteredLiOC6H2-2,6-C(CH3)32-4-CH3)textperiodcenteredC7H8]2: a model for the directed metalation of phosphinamides

Fernández I., F. Ortiz L, Price R.D, Bolton P., Davidson M.G.

Journal of Organometallic Chemistry, 2004, 689, 1890 - 1896. http://dx.doi.org/10.1016/j.jorganchem.2004.03.013

URL: http://www.sciencedirect.com/science/article/pii/S0022328X0400186X

7Li,31P Shift correlation. Application to the structural assignment of benzyllithium complexes of N-methyl-N-benzylphosphinamide

Fernández I., F. Ortiz L.

Chem. Commun., 2004, , 1142-1143. 10.1039/B400994K

URL: http://dx.doi.org/10.1039/B400994K

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